Addition of a chiral copper reagent derived from propargylic oxazolidininone to aldehydes |
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| Authors: | Alouane Nacira Bernaud Frederic Marrot Jerôme Vrancken Emmanuel Mangeney Pierre |
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| Institution: | Laboratoire de Chimie Organique, UMR 761, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie, 75252 Paris Cedex 05, France. |
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| Abstract: | reaction: see text] The copper reagent arising from an optically pure propargylic oxazolidinone was found to react regio- and diastereoselectively with aldehydes, leading, in a one-pot procedure, to the anti homopropargylic amino alcohols derivatives in good yields. |
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