Solid State Synthesis and Hierarchical Supramolecular Self-assembly of Organic Salt Cocrystals

Abstract This paper describes the solid-state synthesis and systematic studies of versatile supramolecular self-assembly of 14 new series of organic salt cocrystals. Hierarchical self-assembly in the solid state utilizes the cooperative interaction of hydrogen bonding, electrostatic and π–π interactions. These salts are crystallized as a highly ordered self-assembly directed by intermolecular non-covalent interaction. Index Abstract Fourteen cocrystals of organic salt have been characterized by single crystal X-ray diffraction and their solid-state packing pattern has been compared. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users.