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二阶导数红外光谱法同时测定两种羧酸盐
引用本文:刘玫. 二阶导数红外光谱法同时测定两种羧酸盐[J]. 光谱实验室, 1997, 14(6): 25-27
作者姓名:刘玫
作者单位:云南大学化学系!昆明市翠湖北路52号,650091,云南教育学院化学系!昆明市,650223,云南大学化学系!昆明市翠湖北路52号,650091
摘    要:本文报道了用二阶导数红外光谱法同时测定同一体系中乙酸钠和苯甲酸钠的实验方法。此法选用乙酸钠和苯甲酸钠的红外特征峰作为分析峰,运用二阶导数法消除两分析峰之间的相互干扰,从而成功的分析出这两种羧酸盐的固体混合物中各组分的含量,其相关系数分别为0.9848和0.9799。

关 键 词:红外光谱 乙酰钠 苯甲酸钠 混合物

Simultaneous Determination of Two Kinds of Carboxylate Salt by the Second Derivative IR-Absorption Spectroscopy
LIU Mei, BI Yunmei, Gu Kun. Simultaneous Determination of Two Kinds of Carboxylate Salt by the Second Derivative IR-Absorption Spectroscopy[J]. Chinese Journal of Spectroscopy Laboratory, 1997, 14(6): 25-27
Authors:LIU Mei   BI Yunmei   Gu Kun
Abstract:The second derivatbe IRspectrOphotometric method for simultaneously determining sodiumacetate and sodinm benzoate is proposed. In this method, two kinds of salt are determinated by theircharacteristic IR peaks,and the interference between the two analyis peaks can be reduced by usingthe second derivative spectrophotometry. The correlation coefficients of so inm acetate and soduimbenzoate are 0. 9848 and 0. 9799 respectively. The method is sample and can be used successfully forthe determination of these kinds of carboxylate salt in their solid misture.
Keywords:IR-Absorption Spectroscopy  Second Derhative Spectrophotometry   Sodium Acetate  Sodium Benzoate
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