| 新型含葡萄糖基手性Salen配体及其Mn3+、Fe3+、Co2+、Cu3+配合物的合成与表征 |
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| 引用本文： | 赵姗姗,赵继全,赵东敏. 新型含葡萄糖基手性Salen配体及其Mn3+、Fe3+、Co2+、Cu3+配合物的合成与表征[J]. 无机化学学报, 2006, 22(6): 1133-1136 |
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| 作者姓名： | 赵姗姗 赵继全 赵东敏 |
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| 作者单位： | 河北工业大学化工学院,天津,300130 |
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| 摘 要： | A novel chiral Salen ligand with a glucose moiety was synthesized from the condensation of 1,2:5,6-di-O-isopropylidene-3-O-methylene-[5-(3-tert-butyl-2-hydroxy benzaldehyde)]-α-D-glucofuranose with (1R,2R)-1,2-diaminocyclohexane. Several chiral complexes of Mn3+, Fe3+, Co2+ and Cu2+ were prepared from this ligand. Both the ligand and the complexes were characterized by elemental analysis, NMR, IR, MS, and UV-Vis.
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| 关 键 词： | 葡萄糖衍生物； 手性金属配合物； Salen配体； Schiff碱； 环己二胺 |
| 文章编号： | 1001-4861(2006)06-1133-04 |
| 收稿时间： | 2006-02-20 |
| 修稿时间： | 2006-05-08 |
Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes |
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| ZHAO Shan-Shan,ZHAO Ji-Quan and ZHAO Dong-Min. Synthesis and Characterization of a Novel Chiral Salen Ligand with a Glucose Moiety and Its Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ) and Cu(Ⅱ) Complexes[J]. Chinese Journal of Inorganic Chemistry, 2006, 22(6): 1133-1136 |
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| Authors: | ZHAO Shan-Shan ZHAO Ji-Quan ZHAO Dong-Min |
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| Affiliation: | School of Chemical Engineering, Hebei University of Technology, Tianjin 300130,School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 and School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 |
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| Abstract: | |
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| Keywords: | glucose derivative chiral metal complex Salen ligand Schiff base diaminocyclohexane |
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