| Hydrothermal Synthesis and Crystal Structure of a Manganese（Ⅱ） Complex：Mn_（1.5）（cbba）_3（phen） |
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| 作者姓名： | 王志涛 李秀梅 王庆伟 |
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| 作者单位： | WANG Zhi-Tao,LI Xiu-Mei(Department of Chemistry, Tonghua Teachers College, Tonghua, Jilin 134002, China);WANG Qing-Wei(Jilin Normal University, Siping, Jilin 136000, China) |
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| 基金项目： | supported by the Science and Technology Research Projects of the Education Department of Jilin Province(No.2009.272) |
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| 摘 要： | A new metal-organic complex Mn1.5(cbba)3(phen)(Hcbba = 2-(4'-chlorine-ben-zoyl)benzoic acid,phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and struc-turally characterized by single-crystal X-ray diffraction,elemental analyses,TG and IR spectro-scopy.The compound crystallizes in triclinic,space group P1 with a = 12.137(2),b = 14.535(3),c = 14.894(3),α = 86.380(3),β = 70.381(3),γ = 72.647(3)°,V = 2360.3(8)3,C107H64Cl6Mn3N4O18,Mr = 2071.14,Dc = 1.457 g/cm3,μ(MoKα) = 0.638 mm-1,F(000) = 1055,Z = 1,the final R = 0.0638 and wR = 0.1905 for 6155 observed reflections(I > 2σ(I)).It exhibits a 3D supramolecular network through hydrogen bonding and π-π stacking interactions.
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| 关 键 词： | 晶体结构 水热合成 phen 锰络合物 超分子网络 金属有机 PHEN 二氮杂菲 |
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