| Synthesis and Crystal Structure of a Polyoxomolybdate Framework Modified by Mn-L Units（L=3-（2-Pyridyl）pyrazole） |
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| 引用本文： | WANG Qing-Wei,LIU Xiao-Xiao,ZHANG Xiu-Tang,LI Xiu-Mei. Synthesis and Crystal Structure of a Polyoxomolybdate Framework Modified by Mn-L Units（L=3-（2-Pyridyl）pyrazole）[J]. 结构化学, 2011, 30(4): 575-579 |
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| 作者姓名： | WANG Qing-Wei LIU Xiao-Xiao ZHANG Xiu-Tang LI Xiu-Mei |
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| 作者单位： | WANG Qing-Wei,LIU Xiao-Xiao(Jilin Normal University, Siping, Jilin 136000, China);ZHANG Xiu-Tang(Advanced Material Institute of Research, Department of Chemistry and Chemical Engineering, Shandong Institute of Education, Jinan, Shandong 250013, China);LI Xiu-Mei(Department of Chemistry, Tonghua Teachers College, Tonghua, Jilin 134002, China) |
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| 基金项目： | supported by the Science and Technology Research Projects of the Education Department of Jilin Province （No.2009.272） |
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| 摘 要： | A new polyoxomolybdate compound,namely {[MnII(L)(4,4?-Hbipy)(H2O)2]2 [Mo5O15(PO4)2]}.2H2O 1(L = 3-(2-pyridyl)pyrazole,4,4'-Hbipy = protonated 4,4'-bipyridine),was designed and synthesized under hydrothermal conditions.Single-crystal X-ray diffraction analysis result reveals that the [Mo5O15(PO4)2]6-cluster in compound 1 links to two MnII cations via the oxygen of PO43-,which is further coordinated by one 3-(2-pyridyl)pyrazole,one 4,4'-Hbipyridine,and two water molecules.
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| 关 键 词： | 吡啶基 钼酸盐 框架结构 吡唑 合成 聚氧 单晶X射线衍射分析 晶体 |
Synthesis and Crystal Structure of a Polyoxomolybdate Framework Modified by Mn-L Units (L = 3-(2-Pyridyl)pyrazole) |
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| WANG Qing-Wei,LIU Xiao-Xiao,ZHANG Xiu-Tang,LI Xiu-Mei. Synthesis and Crystal Structure of a Polyoxomolybdate Framework Modified by Mn-L Units (L = 3-(2-Pyridyl)pyrazole)[J]. Chinese Journal of Structural Chemistry, 2011, 30(4): 575-579 |
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| Authors: | WANG Qing-Wei LIU Xiao-Xiao ZHANG Xiu-Tang LI Xiu-Mei |
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| Abstract: | A new polyoxomolybdate compound, namely {[Mn<'д>(L)(4,4'- Hbipy)(H<,2>O)<,2>]<,2>[Mo<,5>O<,15>(PO<,4>)<,2>]}·2H<,2>O<,1> (L=3-(2-pyridyl)pyrazole, 4,4"-Hbipy=protonated 4,4'-bipyridine), wasdesigned and synthesized under hydrothermal conditions.Single-crystal X-ray diffraction analysisresult reveals that the [Mo<,5>O<,15>(PO<,4>)<,2>]<'6-> cluster in compound 1 links to two Mn<'д> cations via the oxygen of PO<,4><'3->, which is further coordinated by one 3-(2-pyridyl)pyrazole, one 4,4"-Hbipyridine, and two water molecules. |
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| Keywords: | polyoxomolybdate molybdate manganese 3-(2-pyridyl)pyrazole) |
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