Total synthesis of pyrrolidine alkaloid, Radicamine-B via Stille coupling |
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| Authors: | P MalleshamBVD Vijaykumar Dong-Soo Shin S Chandrasekhar |
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| Institution: | a Organic Chemistry Division-I, Indian Institute of Chemical Technology-CSIR, Hyderabad 500 007, India
b Department of Chemistry, Changwon National University, Changwan 641-713, South Korea |
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| Abstract: | Total synthesis of (−) Radicamine-B is achieved in eight steps from (R)-(+)-Garner aldehyde in a stereoflexible manner involving Stille coupling and one-pot domino epoxidation-pyrrolidine formation as key steps. |
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| Keywords: | Radicamine B Garner aldehyde Stille coupling One-pot reaction |
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