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Total synthesis of pyrrolidine alkaloid, Radicamine-B via Stille coupling
Authors:P. MalleshamB.V.D. Vijaykumar  Dong-Soo Shin  S. Chandrasekhar
Affiliation:a Organic Chemistry Division-I, Indian Institute of Chemical Technology-CSIR, Hyderabad 500 007, India
b Department of Chemistry, Changwon National University, Changwan 641-713, South Korea
Abstract:Total synthesis of (−) Radicamine-B is achieved in eight steps from (R)-(+)-Garner aldehyde in a stereoflexible manner involving Stille coupling and one-pot domino epoxidation-pyrrolidine formation as key steps.
Keywords:Radicamine B   Garner aldehyde   Stille coupling   One-pot reaction
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