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| A New Chiral β-Sulfiny Dienophile for Asymmetric Diels-Alder Reaction | |
| 作者姓名： | YANG Teng-Kuei HUNG Shun-Ming CHEN Chin-Zon JIANG Yao-Zhong MI Ai-Qiao Department of Chemistry National Chung-Hsing University Taichung Taiwan 40227 Chengdu Institute of Organic Chemistry Academia Sinica 610015 Chengdu |
| 作者单位： | YANG Teng-Kuei;HUNG Shun-Ming;CHEN Chin-Zon;JIANG Yao-Zhong;MI Ai-Qiao Department of Chemistry，National Chung-Hsing University，Taichung，Taiwan 40227 Chengdu Institute of Organic Chemistry，Academia Sinica，610015 Chengdu |
| 摘 要： | Reaction of a chiral cis-β-sulfinylacrylate, prepared from (1R,2S,3R)-3-mercapto-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, and cyclopentadiene produced Diels-Alder cycloadductswith extremely high diastereoselectivity. |
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