| Synthesis and Structure of （2，2′－Bipyridine） Dibenzoato Copper（Ⅱ） Mono Hydrate |
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| 作者姓名： | Yang Rui-Na Wang Dong-Mei Jin Dou-Man |
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| 作者单位： | Yang Rui-Na;Wang Dong-Mei;Jin Dou-Man(Henan Institute of Chemistry，Zhengzhou 450003 )Wang Hua-Qin;Yang Yao(Nanjing University，Manjing 210008) |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆ（２，２′－Ｂｉｐｙｒｉｄｉｎｅ）ＤｉｂｅｎｚｏａｔｏＣｏｐｐｅｒ（Ⅱ）ＭｏｎｏＨｙｄｒａｔｅ￥ＹａｎｇＲｕｉ－Ｎａ；ＷａｎｇＤｏｎｇ－Ｍｅｉ；ＪｉｎＤｏｕ－Ｍａｎ（ＨｅｎａｎＩｎｓｔｉｔｕｔｅｏｆＣｈｅ...
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Synthesis and Structure of (2, 2′-Bipyridine) Dibenzoato Copper(Ⅱ) Mono Hydrate |
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| Yang Rui-Na,Wang Dong-Mei,Jin Dou-Man.Synthesis and Structure of (2, 2′-Bipyridine) Dibenzoato Copper(Ⅱ) Mono Hydrate[J].Chinese Journal of Structural Chemistry,1994(1). |
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| Authors: | Yang Rui-Na Wang Dong-Mei Jin Dou-Man |
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| Abstract: | Dibenzoyl peroxide undergoes oxidative addition with metallic copper powder and 2, 2'-bipyridine in a mixed solvent (methanol and tetrahydrofuran ) to afford copper(Ⅱ) complex Cu(2, 2'-bipy) (C_6H_5COO)_2]· H_2O. The structure of the cornplex was solved by direct methods and refined by block-diagonal and full-ma-trix least-squares method to a final R of 0. 055 for 2654 independent reflections of I >3σ(I). Crystals are monoclinic,space group P2_1/c , Mr= 479. 78 with cell parameters a= 6. 986(7) , b= 18. 833(1), c= 17. 021(3), β=97. 96(1)°, Z=4, Dc=1. 437g. cm￣(-3), V= 2218. 1. Each copper ion is coordinated by the oxygen atoms of two benzoato groups and the nitrogen atoms of 2. 2'-bipyridine in a planar square geometry. |
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| Keywords: | copper complex oxidative addition crystal structure |
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