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Methyl enol ethers as artefacts in capillary gas chromatographic profiles of aldehyde dimethyl acetals
Authors:T Brosche  D Platt  O Vostrowsky
Abstract:Methyl enol ethers are detected within the capillary gas chromatographic profiles of aldehyde dimethyl acetals derived from human red cell plasmalogens or from a synthetic aldehyde mixture. They arise from the dimethyl acetals via methanol elimination as artefacts of the injection technique. In a nutritional experiment, the probands showed a rising proportion of dimethyl acetals in the phospholipid fraction of their erythrocyte ghosts; this fact is seen as an effect of the lipid composition of the milk fat administered.
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