Character of intermediate radicals in homolytic isomerization of cyclic acetals and their heteroanalogs |
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Authors: | V V Zorin S S Zlot-skii A V Il'yasov D L Rakhmankulov |
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Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions Employing the EPR method and 2-methyl-2-nitrosopropane as the spin trap, we recorded the formation of the radicals
(n = 1 and 2; X = O, N, or a chain composed of C and O atoms; R = H or alkyl) during the photolysis of acetals and their heteroanalogs
in the presence of di-tertbutyl peroxide.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2097–2099, September, 1976.The authors are indebted to A. Sh. Mukhtarov for assistance in running the experiments. |
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