Adducts of Niobium(V) and Tantalum(V) Halogenides. IX. Relative stability of the adducts of the chlorides and bromides with some dialkylchalcogenides |
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Authors: | Ren Good Andr E Merbach |
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Institution: | René Good,André E. Merbach |
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Abstract: | The relative stability of adducts formed by Nb(V) and Ta(V) pentachlorides and bromides with some dimethylchalcogenides and nitriles has been determined by 1H-NMR. in dichloromethane at ? 60°. The stabilities are explained in terms of the HSAB principle and Jørgensen's symbiotic effect. A good correlation exists between the ionisation potential of the valence p orbital of the chalcogen atom in the ligand and the logarithm of the relative stability of the adduct formed with a given acid. |
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