Electrochemical symmetric stochastic diffusion |
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Authors: | B M Grafov |
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Institution: | 1.Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | Symmetric stochastic diffusion in an equilibrium electrochemical ac circuit is studied theoretically. The electrochemical
circuit included double layer capacitance and slow discharge resistance. Electrochemical analog of the stochastic Einstein
formula is found. An equation is obtained for the excess of electrochemical stochastic diffusion. It is shown that an excess
of electrochemical stochastic diffusion increases at high relaxation times in proportion to the observation time. It is found
that excess is related to correlation between the phenomenon of electrochemical stochastic diffusion and the central limiting
theorem. |
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Keywords: | |
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