Electrochemical fabrication of multiplicate palladium hierarchical architectures and their electrocatalysis toward oxidation of formic acid |
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Authors: | Jia Chai Fenghua Li Yu Bao Shiwei Liu Qixian Zhang Li Niu |
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Institution: | (1) Engineering Laboratory for Modern Analytical Techniques, c/o State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate University of the Chinese Academy of Sciences, Changchun, 130022, Jilin, Peoples Republic of China; |
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Abstract: | Dendritic, cactoid, splintery flowers-like and spinous flowers-like micro/nano-Pd hierarchical architectures were successfully
deposited on the conductive substrates without assistance of any templates. Distinct from other general electrodeposition
at a constant potential or cyclic potential, we utilized pulse potentials as deposition and dissolution potential, which were
controlled by a simple and convenient electrochemical method—differential pulse amperometry. It was found that the morphologies
of these novel micro/nanoparticles could be regulated with different pulse potentials. The resulting nanostructures were characterized
by scanning electron microscopy and X-ray diffractometry. The results show that series of Pd micro/nanoparticles were bounded
on the different index facets. It means that the growth direction could be effectively controlled by regulating the pulse
potentials. Moreover, the as-synthesized Pd micro/nanoparticles also exhibited strikingly difference in catalytic activity
toward electrooxidation of formic acid. |
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Keywords: | |
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