Specific interactions including imidazolium andN-methylimidazolium lons. I. Interactions with the picrate anion |
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| Authors: | H Collaer M C Haulait-Pirson P Huyskens |
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| Institution: | (1) Laboratory of Physical and Radiation Chemistry, University of Louvain-Celestijnenlaan, 200-F, 3030 Heverlee, Belgium |
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| Abstract: | The conductances of solutions of methylimidazolium and imidazolium picrate (MeImHPic and ImHPic) in nitrobenzene-benzene mixtures (27.2–. These triple ions are highly stabilized by the hydrogen bond between the second NH group of the ion pair and the second picrate ion. Values of the formation constants for the ion pair ImHPic and for the triple ion PicImHPic– have been calculated and are discussed. |
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| Keywords: | Conductivity hydrogen bonds imidazolium picrate ion pairs 1-methylimidazolium picrate triple ions |
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