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Rate constants for the gas-phase reactions of O3 with selected organics at 296 K
Authors:Roger Atkinson  Sara M Aschmann  Dennis R Fitz  Arthur M Winer  James N Pitts
Abstract:Rate constants for the gas-phase reactions of O3 with ethene, propene, 1-hexene, 1-heptene, styrene, o-, m-, and p-cresol, o- and m-xylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ± 2 K. The rate constants ranged from <5 × 10?21 cm3 molecule?1 s?1 for m-xylene to 2.16 × 10?17 cm3 molecule?1 s?1 for styrene, with those for ethene, propene, and 1-hexene being in excellent agreement with literature data.
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