Mass spectral fragmentation pattern of 5-methyl-4-[(phenylamino)methylene]-2,4-dihydro-3h-pyrazol-3-one and its 2-methyl and 2-phenyl derivatives |
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Authors: | Neil G Keats Jean E Rockley Lindsay A Summers |
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Abstract: | The mass spectral fragmentation patterns of 5-methyl-4-(phenylamino)methylene]-2,4-dihydro-3H-pyrazol-3-one and its 2-methyl and 2-phenyl derivatives have been elucidated. The principal initial fragmentation route involves rupture of the exocyclic CH-NH bond. Minor routes involve loss of H, OH and C6H5 from the molecular ion and rupture of the pyrazolone ring. |
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