Sandwich-shaped silver(I) metallomacrocycles encapsulating a XF6(2-) (X = Si, Ge and Sn) anion |
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| Authors: | Maekawa Masahiko Kitagawa Susumu Kuroda-Sowa Takayoshi Munakata Megumu |
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| Institution: | Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka 577-8502, Japan. maekawa@rist.kindai.ac.jp |
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| Abstract: | A series of sandwich-shaped complexes based on two square tetranuclear Ag(I) metallomacrocycles, Ag4(pprd)4]2(XF6)]-(BF4)6.8MeNO2 (pprd = 4-(2-pyridyl)pyrimidine; X = Si, Ge and Sn), in which a XF6(2-) anion is encapsulated, were prepared and their structures were characterized both in the solid state and solution. |
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