| 氰根桥连的异金属配位聚合物{[Ni(pn)2][Fe(CN)4(bipy)]}2·3H2O(pn=1,3-丙二胺,bipy=2,2′-联吡啶)的合成与结构 |
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| 引用本文： | 常菲,孙豪岭,高松.氰根桥连的异金属配位聚合物{[Ni(pn)2][Fe(CN)4(bipy)]}2·3H2O(pn=1,3-丙二胺,bipy=2,2′-联吡啶)的合成与结构[J].无机化学学报,2002,18(1):95-98. |
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| 作者姓名： | 常菲 孙豪岭 高松 |
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| 作者单位： | 北京大学化学与分子工程学院,稀土材料化学及应用国家重点实验室,北京,100871 |
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| 基金项目： | 国家重点基础研究发展规划项目(No.G1998061305);国家杰出青年科学基金和国家自然科学基金资助项目(No.20023005,29831010),国家教育部资助优秀年轻教师基金资助. |
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| 摘 要： | 以Fe(CN)4(bipy)]2-为建筑块和Ni(pn)2]2+在水溶液中反应,合成了{Ni(pn)2]Fe(CN)4(bipy)]}2·3H2O(pn=1,3-丙二胺)。通过X-射线单晶衍射确定了其晶体结构。该配合物属单斜晶系,P21/n空间群,晶胞参数为:a
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| 关 键 词： | 配位聚合物 晶体结构 氰根 螺旋链 |
| 修稿时间： | 2001年10月30 |
Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Coordination Polymer{ [Ni(pn)2] [Fe(CN)4(bipy) ] }2 · 3H2O (pn = 1, 3-diaminopropane, bipy = 2, 2′-bipyridine) |
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| CHANG Fei,SUN Hao-Ling and GAO Song.Synthesis and Crystal Structure of a Cyano-bridged Bimetallic Coordination Polymer{ [Ni(pn)2] [Fe(CN)4(bipy) ] }2 · 3H2O (pn = 1, 3-diaminopropane, bipy = 2, 2′-bipyridine)[J].Chinese Journal of Inorganic Chemistry,2002,18(1):95-98. |
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| Authors: | CHANG Fei SUN Hao-Ling and GAO Song |
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| Institution: | State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 and State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 |
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| Abstract: | |
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| Keywords: | coordination polymer crystal structure cyanide helical chain |
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