Structure and characterization of bis(N-p-chloro-phenyl-salicylideneaminate) Schiff base copper(II) complex: Cu[N-p-Cl-Ph-Sal]2 |
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Authors: | Qiaofeng Han Fangfang Jian Lude Lu Xujie Yang Xin Wang |
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Institution: | (1) Materials Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing, 210094, People's Republic of China |
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Abstract: | The crystal and molecular structure of the title compound has been determined by X-ray crystallography. It crystallizes in the monoclinic system, space group P21/c, with lattice parameters a = 13.678(3), b = 10.729(2), c = 8.1996(2) Å, = 98.96°, V = 1188.7(4) Å3, and Z = 4. The crystal structure contains two centrosymmetric molecules of bis (N-p-chloro-phenyl-salicylideneaminate) Schiff base copper(II). Copper(II) ion is coordinated in a slightly distorted trans square-planar configuration, the distortion consisting of a reduction of the N–Cu–O angle with the chelate rings from the ideal value of 90°. The p-chlorophenyl rings with salicylidene moieties form a dihedral angle of 38.96°. |
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Keywords: | copper complex salicylideneaminate Schiff base square-planar |
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