| 酞菁和酞菁铜的三阶非线性光学性质 |
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| 引用本文： | 封继康,李君,孙家钟.酞菁和酞菁铜的三阶非线性光学性质[J].化学学报,1994,52(6):539-544. |
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| 作者姓名： | 封继康 李君 孙家钟 |
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| 作者单位： | 吉林大学化学系;吉林大学理论化学研究所 |
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| 基金项目： | 国家自然科学基金，吉林大学分子光谱与分子结构开放实验室资助的课题. |
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| 摘 要： | 用INDO/SDCI方法研究了酞菁和酞菁铜的电子结构, 紫外-可见光谱, 三阶非线性光学系数及其色散效应, 发现酞菁铜中Cu^2+对γ的贡献很小, 故酞菁与酞菁铜的γ几乎相等, 我们的计算结果对此进行了合理的解释。
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| 关 键 词： | 光学性质 量子化学 染料 电子结构 微扰论 非线性光学 微分重叠间忽略近似 三阶导数 酞菁P 酞菁 |
The nonlinear third-order optical properties of phthalocyanine and copper phthalocyanine |
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| FENG JIKANG,LI JUN,SUN JIAZHONG.The nonlinear third-order optical properties of phthalocyanine and copper phthalocyanine[J].Acta Chimica Sinica,1994,52(6):539-544. |
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| Authors: | FENG JIKANG LI JUN SUN JIAZHONG |
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| Abstract: | The electronic structure, UV-vis spectrum, nonlinear third-order optical susceptibility and dispersion of phthalocyanine(H2Pc) and copper phthalocyanine(CuPc) were studied by using INDO/SDCI method. It was discovered that the contribution of Cu2+ ion to g is very little in CuPc, so the g of CuPc is almost equal to g of H2Pc. It can be explained reasonably from the authors' calculated results. |
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| Keywords: | OPTICAL PROPERTIES QUANTUM CHEMISTRY DYES ELECTRONIC STRUCTURE PERTURBATION THEORY NON LINEAR OPTICS INTERMEDIATE NEGLECT OF DIFFERENTIAL OVERLAP APPROXIMATION (IND THIRD DERIVATIVE ZINC PHTHALOCYANINE PHTHALOCYANIN (=PHTHALOCYANINE) |
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