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复合物邻二甲苯…NH3(ND3)分子间的振动
引用本文:胡义华,熊建文,周金运,王小涓,杨世和. 复合物邻二甲苯…NH3(ND3)分子间的振动[J]. 物理化学学报, 2001, 17(6): 570-572. DOI: 10.3866/PKU.WHXB20010620
作者姓名:胡义华  熊建文  周金运  王小涓  杨世和
作者单位:Department of Applied Physics,Guangdong University of Techlonogy,Guangzhou 51 0090;Department of Physics,South China Normal University ,Guangzhou 510030;Department of Chemistry,Hong Kong University of Science & Techlonogy,Hong Kong
基金项目:香港政府自然科学基金资助
摘    要:

关 键 词:共振双光子电离谱  分子间范德华振动  
收稿时间:2000-12-25
修稿时间:2000-12-25

Vibrations between TwoMolecules in the Complex o-xylene
Hu Yi-Hua. Vibrations between TwoMolecules in the Complex o-xylene[J]. Acta Physico-Chimica Sinica, 2001, 17(6): 570-572. DOI: 10.3866/PKU.WHXB20010620
Authors:Hu Yi-Hua
Affiliation:Department of Applied Physics,Guangdong University of Techlonogy,Guangzhou 51 0090;Department of Physics,South China Normal University ,Guangzhou 510030;Department of Chemistry,Hong Kong University of Science & Techlonogy,Hong Kong
Abstract:Resonant two photon ionization spectra of S1←S0 transition in complex o xylene…NH3(ND3) in supersonic molecular beam are observed using resonant two photon ionization,together with time of flight mass spectrometry.The spectra exhibit rich information on the complex intermolecular vdW vibrational modes.We have tentatively assigned all the observed spectral features.By analyzing the spectra,the stretching vibrational frequencies and two bending vibrational frequencies of the the complex are obtained.The structure of the complex has been obtained by ab initio computation method.
Keywords:Spectrum of resonant two photon ionization  van der Waals vibrations between molecules
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