2,5-Dichloro-4,4-ethylenedioxy-3-phenylsulfonyl-2-cyclopentenone in Nucleophilic Substitution and Addition Reactions |
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| Authors: | N. A. Ivanova F. G. Usmanova M. S. Miftakhov |
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| Affiliation: | (1) Institute of Organic Chemistry, Ufa Research Center, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054, Russia |
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| Abstract: | 2,5-Dichloro-4,4-ethylenedioxy-3-phenylsulfonyl-2-cyclopentenone reacts with diethyl malonate potassium salt according to the AdNE pattern with replacement of chlorine atoms at the double C=C bond, while the reaction of the same substrate with allylcuprate is not selective, and it follows several pathways.__________Translated from Zhurnal Organicheskoi Khimii, Vol. 41, No. 4, 2005, pp. 562–566.Original Russian Text Copyright © 2005 by Ivanova, Usmanova, Miftakhov. |
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