Electronic influence of water adsorbed on ZnO in H2 and Co oxidation |
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Authors: | M Guelton J P Bonnelle and J P Beaufils |
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Institution: | (1) Laboratoire de Catalyse et Physicochimie des Surfaces Equipe de Recherche Associée au C.N.R.S., Université des Sciences et Techniques de Lille, B. P. 36, 59650 Villeneuve d'Ascq, France |
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Abstract: | In this paper we calculate the effect of surface OH/OH– on the simultaneous adsorption of H2 and O2 on ZnO. A quantitative comparison between H2 and CO oxidation rates shows that the two mechanisms are similar for the same water recovery on ZnO.
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