Synthesis of α,β-disubstituted ferrocenes via a ferrocenylepoxide intermediate. Preparation and catalytic activity of a new chiral ferrocenyloxazoline |
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| Authors: | Angela Patti Matthias Lotz Paul Knochel |
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| Institution: | a Istituto CNR per lo Studio delle Sostanze Naturali di Interesse Alimentare e Chimico-Farmaceutico, Via del Santuario 110, I-95028 Valverde CT, Italy;b Department of Chemistry of Ludwig-Maximilians-University, Butenandtstrasse 5-13, 81377 Munich, Germany |
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| Abstract: | A short synthesis of the chiral oxazoline 10 (>95% e.e.) in six steps from chloroacetylferrocene is described. The ligand can be used successfully in an asymmetric Pd(0)-catalyzed allylic alkylation reaction. |
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