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Total synthesis of (+/-)-terpestacin and (+/-)-11-epi-terpestacin |
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| Authors: | Berger Gideon O Tius Marcus A |
| Institution: | University of Hawaii, Chemistry Department, Honolulu, Hawaii 96822, USA. |
| Abstract: | The total synthesis of racemic terpestacin and 11-epi-terpestacin using the allene ether Nazarov reaction as the key step is described. All stereochemistry is derived from the stereogenic carbon atom that is formed during the Nazarov reaction. |
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