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3,6-Didecyloxyphthalonitrile as a starting compound for the selective synthesis of phthalocyanines of the ABAB type
Authors:Kudrik  E. V.  Nikolaev  I. Yu.  Shaposhnikov  G. P.
Affiliation:(1) Chemistry and Technology, Ivanovo State University, 7 prosp. F. Engel'sa, 153460 Ivanovo, Russian Federation
Abstract:Reactions of 3,6-dipentyloxy- and 3,6-didecyloxyphthalonitriles with lithium pentoxide in pentan-1-ol were studied. 3,6-Didecyloxyphthalonitrile can be used for the preparation of both the corresponding octasubstituted phthalocyanines and phthalocyanines of the ABAB type.
Keywords:phthalocyanine  asymmetrical substitution  selectivity  isoindole derivatives  phthalonitrile
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