11B and13C NMR studies on silica modified by borate esters |
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Authors: | V. A. Kasperskii V. V. Brei Yu. I. Gorlov A. A. Chuiko |
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Affiliation: | (1) Surface Chemistry Institute, Ukrainian Academy of Sciences, Kiev |
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Abstract: | 11B and13C NMR has been applied along with programmed desorption and boron analysis to the surface of aerosil specimens modified by trimethoxyborane and dimethoxybutyl-borane. It is concluded that methanol is coordinated to the boron atoms in the dimethoxyborosilyl groups.Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 24, No. 1, pp. 118–121, January–February, 1988. |
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