| 锕系配合物中Vander Waals能与配位键能之间的平衡I: |
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| 引用本文： | 冯锡章. 锕系配合物中Vander Waals能与配位键能之间的平衡I:[J]. 化学学报, 1987, 45(1): 65-67 |
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| 作者姓名： | 冯锡章 |
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| 作者单位： | 中国科学院高能物理研究所应用部 |
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| 摘 要： | 对铀的几个络合物的配位键和Van der Waals能之间的平衡进行分析研究,发现在配位原子间配合键能和最大Van der Waals引力能几乎一致,这有力地支持了堆积模型将成为这一模型进一步发展的基础.
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| 关 键 词： | 晶体结构测定 化学键 草酸根络合物 络合物化学 键能 锕系络合物 范德华键 草酸铀 |
Balance between coordination bond and Van der Waals energies of the complex compounds of actinides I: |
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| FENG XIZHANG. Balance between coordination bond and Van der Waals energies of the complex compounds of actinides I:[J]. Acta Chimica Sinica, 1987, 45(1): 65-67 |
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| Authors: | FENG XIZHANG |
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| Abstract: | By analyzing the balance between the coordination bond and van der Waals energies of several U complexes, the coordination bond energy and the max. van der Waals attractive energy between the coordination atoms were found nearly identical. This is strong support for the packing model, and can be the foundation for the future development of that model. |
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| Keywords: | CRYSTAL STRUCTURE DETERMINATION CHEMICAL BONDS OXALATO COMPLEX COORDINATE CHEMISTRY BOND ENERGY ACTINIDE COMPLEX VAN DER WAALS BONDS URAN OXALATE |
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