| Solid Synthesis and Crystal Structure of Compound [（PPh3）3Cu2MoOS3] |
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| 引用本文： | 林振光,黄小荥,等. Solid Synthesis and Crystal Structure of Compound [（PPh3）3Cu2MoOS3][J]. 结构化学, 1996, 15(4): 333-336 |
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| 作者姓名： | 林振光 黄小荥 等 |
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| 作者单位： | Lin Zhen-Guang(Department of Chemistry，Fujian Normal University，Fuzhou，Fujian，350007 |
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| 摘 要： | ＳｏｌｉｄＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＣｏｍｐｏｕｎｄ［（ＰＰｈ_３）_３，Ｃｕ_２ＭｏＯＳ_３］ＬｉｎＺｈｅｎ－Ｇｕａｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，ＦｕｊｉａｎＮｏｒｍａｌＵｎｉｖｅｒｓｉｔｙ，Ｆｕｚ...
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| 关 键 词： | 固态 合成 晶体结构 三苯基膦配位体 钼 铜 硫 |
Solid Synthesis and Crystal Structure of Compound[ (PPh_3 )_3,Cu_2MoOS_3] |
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| Lin Zhen-Guang. Solid Synthesis and Crystal Structure of Compound[ (PPh_3 )_3,Cu_2MoOS_3][J]. Chinese Journal of Structural Chemistry, 1996, 15(4): 333-336 |
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| Authors: | Lin Zhen-Guang |
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| Affiliation: | [1]DepartmentofChemistry,FujianNormalUniversity,Fuzho [2]DepartmentofChemistry,FujianN |
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| Abstract: | A brown-red compound [( PPh_3 )_2Cu_2MoOS_3] was synthesized through a solid state reaction. The crystal is monoclinic, space group P2_1/c with α =19. 316(5), b=10. 46(1), c=24. 738(8) A, β=97. 01(2)°, V=4946(9) A￣3, Z=4. The unique Mo atom has a distorted tetrahedral coordination geometry, one Cu atom has a distorted tetrahedral coordination geometry, too, but the other has a trigonal planar environment. The core , Cu_2MoOS_3, shows a butterfly-like structure. |
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| Keywords: | solid state synthesis molybdenum-copper-sulfur crystal structure |
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