| Solid Synthesis and Crystal Structure of Compound [（PPh3）3Cu2MoOS3] |
| |
| 引用本文： | 林振光,黄小荥,等.Solid Synthesis and Crystal Structure of Compound [（PPh3）3Cu2MoOS3][J].结构化学,1996,15(4):333-336. |
| |
| 作者姓名： | 林振光 黄小荥 等 |
| |
| 作者单位： | Lin Zhen-Guang(Department of Chemistry，Fujian Normal University，Fuzhou，Fujian，350007 |
| |
| 摘 要： | ＳｏｌｉｄＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＣｏｍｐｏｕｎｄ［（ＰＰｈ_３）_３，Ｃｕ_２ＭｏＯＳ_３］ＬｉｎＺｈｅｎ－Ｇｕａｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＣｈｅｍｉｓｔｒｙ，ＦｕｊｉａｎＮｏｒｍａｌＵｎｉｖｅｒｓｉｔｙ，Ｆｕｚ...
|
| 关 键 词： | 固态 合成 晶体结构 三苯基膦配位体 钼 铜 硫 |
Solid Synthesis and Crystal Structure of Compound[ (PPh_3 )_3,Cu_2MoOS_3] |
| |
| Lin Zhen-Guang.Solid Synthesis and Crystal Structure of Compound[ (PPh_3 )_3,Cu_2MoOS_3][J].Chinese Journal of Structural Chemistry,1996,15(4):333-336. |
| |
| Authors: | Lin Zhen-Guang |
| |
| Institution: | [1]DepartmentofChemistry,FujianNormalUniversity,Fuzho [2]DepartmentofChemistry,FujianN |
| |
| Abstract: | A brown-red compound ( PPh_3 )_2Cu_2MoOS_3] was synthesized through a solid state reaction. The crystal is monoclinic, space group P2_1/c with α =19. 316(5), b=10. 46(1), c=24. 738(8) A, β=97. 01(2)°, V=4946(9) A￣3, Z=4. The unique Mo atom has a distorted tetrahedral coordination geometry, one Cu atom has a distorted tetrahedral coordination geometry, too, but the other has a trigonal planar environment. The core , Cu_2MoOS_3, shows a butterfly-like structure. |
| |
| Keywords: | solid state synthesis molybdenum-copper-sulfur crystal structure |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
