| 超电容器复合活性炭电极的制备及性能研究 |
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| 引用本文： | 孟庆函,刘玲,凌立成.超电容器复合活性炭电极的制备及性能研究[J].电子元件与材料,2003,22(10):4-6. |
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| 作者姓名： | 孟庆函 刘玲 凌立成 |
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| 作者单位： | 1. 北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029
2. 中科院山西煤炭化学研究所煤转化国家重点实验室,山西,太原,030001 |
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| 基金项目： | 北京化工大学青年教师基金(QN0249)，国家自然科学基金(50272070)，山西青年基金(20011026) |
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| 摘 要： | 用高比表面积活性炭作为原料,酚醛树脂为粘结剂,在120℃高温下粘结成型制备系列超电容器用固体活性炭电极,改变酚醛树脂添加量考察不同炭化温度对复合活性炭电极炭化收率的影响。实验发现,随着炭化温度的提高,复合活性炭电极的炭化收率呈逐渐降低的趋势,炭化温度高于800℃时复合活性炭电极比电容量下降。酚醛树脂掺杂量多时收率降低。另外在酚醛树脂中加入固化剂可提高其炭化收率。不同组成的复合活性炭电极中,微孔活性炭含量大,则比电容量高。
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| 关 键 词： | 超电容器 活性炭 成型 |
| 文章编号： | 1001-2028(2003)10-0004-03 |
| 修稿时间： | 2003年6月2日 |
Composite Activated Carbon Electrodes of Supercapacitors: Preparation and Properties |
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| MENG Qing-han,LIU Ling,LING Li-cheng.Composite Activated Carbon Electrodes of Supercapacitors: Preparation and Properties[J].Electronic Components & Materials,2003,22(10):4-6. |
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| Authors: | MENG Qing-han LIU Ling LING Li-cheng |
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| Institution: | MENG Qing-han1,LIU Ling1,LING Li-cheng2 1. The Key Laboratory of Science and Technology of Controllable Chemical Reactions BUCT,Ministry of Education,Beijing University of Chemical Technology,Beijing 100029,China, 2. State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China) |
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| Abstract: | Composite electrodes for supercapacitors were prepared by sintering at 120 篊, with activated carbons (ACs) of high specific surface area as material and phenolic resin (PR) as binder. The effect of PR-content and carbonization temperature on the yield of the formed ACs was investigated. The results show that the yield decreases obviously with the increase of carbonization temperature and the increase of PR-content. Yield can be increased by adding in PR some curing agent. The specific capacitance of formed activated carbon electrode increases with the increase of microporous AC-content, and decreases negligibly when the carbonization temperature is above 800℃. |
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| Keywords: | supercapacitors activated carbon formation |
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