Determining the Maximum Excess Heat of Solution Differentials Using the Carnot Cycle Temperature Efficiency |
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| Authors: | David Van Den Einde |
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| Institution: | (1) 1284 170th St., Bejou, Minnesota 56516, USA |
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| Abstract: | The (T
1−T
2)/T
1 efficiency of a very small temperature differential thermodynamic cycle operating near a solvent’s critical locus, where
T
1 is the higher temperature and T
2 the lower, is shown to be a simple tool for determining the maximum difference in the excess heat of solution between the
cycle’s low-temperature liquid side and its high-temperature supercritical fluid side. |
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| Keywords: | Solvent Thermodynamic cycle Solubility Positive Second Law of Thermodynamics |
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