Ruthenium-catalyzed tertiary amine formation from nitroarenes and alcohols |
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| Authors: | Feng Chao Liu Yong Peng Shengming Shuai Qi Deng Guojun Li Chao-Jun |
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| Institution: | Key Laboratory for Environmental Friendly Chemistry and Application of the Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China. |
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| Abstract: | A highly selective ruthenium-catalyzed C-N bond formation was developed by using the hydrogen-borrowing strategy. Various tertiary amines were obtained efficiently from nitroarenes and primary alcohols. The reaction tolerates a wide range of functionalities. A tentative mechanism was proposed for this direct amination reaction of alcohols with nitroarenes. |
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