PMR study of the degenerate electron transfer between 1,2,3-trimethyl-2-phenylbenzimidazoline and its cation radical |
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| Authors: | A. N. Suslov A. S. Morkovnik G. S. Borodkin |
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| Affiliation: | (1) Research Institute for Physical and Organic Chemistry, University of Rostov, USSR |
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| Abstract: | The degenerate electron transfer (electron exchange) between 1,2,3-trimethyl-2-phenylbenzimidazoline and the perchlorate of its radical cation has been studied by PMR in deuteriated aceonitrile. We have determined rate constants and activation parameters for this process, and also some hyperfine interaction (HFI) constants for the cation radical, inaccessible by ESR measurements.Translated from Teoreticheskie i Éksperimental'naya Khimiya, Vol. 26, No. 6, pp. 658–663, November–December, 1990. |
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