Calorimetric study of the BrO3?/Ce4+/cyclohexanone and BrO3?/Ce4+/cyclopentanone oscillating systems |
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| Authors: | V J Farage and D Janjic |
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| Institution: | (1) Department of Physical Chemistry 30, University of Geneva, quai Ernest-Ansermet, CH-1211 Geneve 4, Switzerland |
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| Abstract: | The heat output (Q) during the  induction period of a Belousov-Zhabotinskii oscillating reaction usually evolves at a constant rate /6/; we observe in the BrO
3
–
/Ce4+/Cyclohexanone system a sudden change in the slope of the function Q=f(t), which corresponds to the beginning of the quasistationary phase /3/.
          (Q)                -   ; BrO
3
–
/Ce+4/   Q=f(t), .
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