Nitrogen-doped carbon nanotube spheres as metal-free catalysts for the partial oxidation of H2S |
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Institution: | 1. Institut de Chimie et Procédés pour l’Energie, l’Environnement et la Santé (ICPEES), ECPM, UMR 7515 du CNRS-Université de Strasbourg, 25 rue Becquerel, 67087 Strasbourg Cedex 02, France;2. Unité de Catalyse et Chimie du Solide (UCCS), UMR 8181 CNRS-Université de Lille-1, Sciences et Technologies, 59655 Villeneuve d''Ascq cedex, France;3. Ha-Noi University of Mining and Geology, Dong Ngac Tu Liem, Ha Noi, Viet Nam |
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Abstract: | Nitrogen-doped carbon nanotubes (N-CNTs) with macroscopic shaping were synthesized by a coagulation route using alginate as a coagulating agent and the as-synthesized sample was used as metal-free catalysts in the partial oxidation of H2S into elemental sulfur. The N-CNT beads display a relatively high desulfurization activity along with a high stability as a function of time on stream. The desulfurization performance of the N-CNT beads was also measured and compared to that of the Fe2O3/SiC catalyst. The N-CNT beads display a higher desulfurization activity under the similar reaction conditions with, however, lower sulfur selectivity due to the problem of diffusion of the reactant through the bead porosity. |
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Keywords: | Nitrogen-doped carbon nanotubes Macroscopic shape Metal-free catalyst Desulfurization |
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