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Nanocomposites with different metals as magnetically separable nanocatalysts for oxidation of aldehydes
Affiliation:Department of Chemical Engineering, North Tehran Branch, Islamic Azad University, PO Box 19585/936, Tehran, Iran
Abstract:In this study, two metals were chosen for composing two different nanocatalysts. Zinc acetate and nickel chloride were used to prepare two nanocatalysts from acetanilide anchored to functionalized silica-coated Fe3O4 magnetic nanoparticles. They were identified using scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, and gas chromatography–mass spectrometry. These nanocatalysts were used for the oxidation of the following aldehydes: 3-hydroxybenzaldehyde, 4-methoxybenzaldehyde, and 3-nitrobenzaldehyde. High efficiency, stability, recoverability, recyclability, and selectivity were achieved using these nanocatalysts.
Keywords:Magnetic nanocatalyst  Acetanilide  Nickel chloride  Aldehyde
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