Dynamic behaviour of Ru and Ru-Pt complexes containing tetrahedro-P4 ligand |
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| Authors: | Mirabello Vincenzo Caporali Maria Gallo Vito Gonsalvi Luca Ienco Andrea Latronico Mario Mastrorilli Piero Peruzzini Maurizio |
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| Affiliation: | Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici, Sesto Fiorentino, Firenze, Italy. |
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| Abstract: | Dynamic processes involving the P(4) cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)(2)(H)(η(1)-P(4))]BF(4) and for the bimetallic derivative trans-[Ru(dppm)(2)(H)(μ ,η(1:2)-P(4)){Pt(PPh(3))(2)}]BF(4) as demonstrated by NMR experiments and DFT calculations. |
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