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Three-step synthesis of cyclopropyl peptidomimetics
Authors:Dunlap Norma  Lankford Kevin R  Pathiranage Anuradha Liyana  Taylor Jessica  Reddy Nikhil  Gouger Daniel  Singer Phillip  Griffin Kent  Reibenspies Joseph
Institution:Middle Tennessee State University, Department of Chemistry, Murfreesboro, Tennessee 37132, USA. ndunlap@mtsu.edu
Abstract:An efficient approach to novel cyclopropyl peptidomimetics has been developed. The synthetic route involves a cyclopropanation using ethyl (dimethylsulfuranylidene)acetate (EDSA) as the key step and affords a cyclopropyl peptidomimetic core in three steps from protected amino acid Weinreb amides.
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