Aurophilic interactions as a subject of current research: an up-date |
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Authors: | Schmidbaur Hubert Schier Annette |
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Affiliation: | Department Chemie, Technische Universit?t München, Lichtenbergstreet 4, 85747 Garching b. M., Germany. H.Schmidbaur@lrz.tum.de |
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Abstract: | Recently accumulated experimental evidence for aurophilic interactions in and between molecular gold(I) compounds and the results of pertinent theoretical calculations are reviewed for the period from 2007 to mid-2011. The influence of the intra- and intermolecular bonding contacts between the closed-shell metal centres, Au-Au, on the molecular and crystal structures, and the consequences of these effects for the chemical and physical properties of gold compounds are summarized for the various classes of mono- and polynuclear systems. The literature survey builds on the contents of previous reviews and relates new experimental and theoretical findings to earlier observations (353 references). |
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