Assembly of a luminescent core-shell nanocluster featuring a Ag34S26 shell and a W6O21(6-) polyoxoanion core |
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| Authors: | Zhou Kun Qin Chao Li Hai-Bin Yan Li-Kai Wang Xin-Long Shan Guo-Gang Su Zhong-Min Xu Chuang Wang Xiu-Li |
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| Institution: | Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, People's Republic of China. |
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| Abstract: | Bridging between silver clusters and polyoxoanion clusters, the first 1D assembly, Ag(34)(S(t)Bu)(26)(W(6)O(21))(CF(3)COO)](CF(3)COO)·Et(3)N·20CH(3)OH (1), based on POM-templated silver-thiolate nanoclusters featuring a Ag(34)(S(t)Bu)(26)(CF(3)COO)](7+) shell and a W(6)O(21)](6-) core is reported. This novel core-shell nanocluster possesses nanoscopic morphology, displays intense deep-blue emission in solution under ambient conditions and also shows special electrochemical properties. |
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