|
|||||
|
|
The mechanism of enzymatic and biomimetic oxidations of aromatic sulfides and sulfoxides |
|
| Authors: | Enrico Baciocchi Osvaldo Lanzalunga Francesco Marconi |
| Affiliation: | Dipartimento di Chimica, Università “La Sapienza” and Centro CNR di Studio sui Meccanismi di Reazione, P.le A. Moro 5, 00185 Rome, Italy |
| Abstract: | Biomimetic and enzymatic oxidations of benzyl sulfides and sulfoxides lead to products (sulfoxides or sulfones) different from those obtained with bona fide electron transfer oxidations (products of C---H and/or C---S bond cleavage), which suggests the operation of an oxygen transfer mechanism. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |