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N-heterocyclic carbenes as ligands in high-valent molybdenum and tungsten complexes |
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| Authors: | Wolfgang A Herrmann Gerhard M Lobmaier and Martina Elison |
| Institution: | Anorganisch-chemisches Institut der Technischen Universität München, Lichtenbergstraβe 4, D-85747 Garching b., München, Germany |
| Abstract: | Oxometal complexes of molybdenum and tungsten in high oxidation states from stable adducts with 1,3-dimethylimidazoline-2-ylidene (L) 1. The first ‘carbene’ complexes of molybdenum(VI) MoO2Cl(L)3]Cl (3a) and tungsten(VI) WO2Cl2(L)2 (4b) are reported. |
| Keywords: | Molybdenum(VI) Tungsten(VI) Imidazoline-2-ylidene Heterocyclic carbenes |
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