Preparation of Multilayered 1,2-Ethylene-silica Nanotubes Through a Dual-templating Approach |
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Authors: | WU Li-min BI Li-feng WANG Si-bing LI Bao-zong LI Yi YANG Yong-gang |
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Institution: | College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China |
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Abstract: | Multilayered 1,2-ethylene-silica nanotubes were prepared with cetyltrimethylammonium bromide(CTAB) as a template and (S)-β-citronellol(CN) as a co-structure-directing agent. For a better understanding of the formation of this structure, the CN/CTAB molar ratio in the reaction mixtures was tuned. With increasing the CN/CTAB molar ratio, a hexagonal to lamellar phase trasformation was observed; and the morphologies of 1,2-ethylene-silica changed from rod to vesicle and then to tubular structure. CN droplets were proposed as the templates for the nanotubes. The obtained samples were characterized by means of X-ray diffraction, nitrogen sorption, field emission scanning electron microscopy and transmission electron microscopy. |
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Keywords: | 1 2-Ethylene-silica nanotube Chiral alcohol Phase transformation |
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