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Effective VTeO/SBA-15 Catalyst Prepared by Precursor Method for the Selective Oxidation of Propane to Acrolein
Authors:Mao-ying FENG  Chuan-jing HUANG  Wei-zheng WENG  Hui-lin WAN  Qin XU  Zhao-hui ZHOU
Affiliation:College of Chemistry and Chemical Engineering, State Key Laboratory for Physical Chemistry of Solid Surface, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Xiamen University, Xiamen 361005, P. R. China
Abstract:Precursor decomposition was used for the preparation of VTeO/SBA-15 catalyst for the selective oxidation of propane to acrolein.The catalyst shows a better performance compared with those prepared by conventional impregnant method.A yield of 9.3% of acrolein was achieved with 2% V Ioadings at 500℃.XRD,N2-adsorption,H2-TPR,Py-IR and XPS measurements were used to unclose the relationship between the structure and performance of the catalyst.
Keywords:Acrolein  Propane  Vanadium catalyst  Precursor decomposition
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