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One-Step Synthesis of the Vicinal Dinitroguaianolides Achillin and Grossmisin |
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| Authors: | O V Alebastrov V A Raldugin I Yu Bagryanskaya Yu V Gatilov M M Shakirov A T Kulyyasov S M Adekenov |
| Institution: | (1) Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, pr. Akad. Lavrent'eva, 9;(2) Ministry of Education and Science, Republic of Kazakhstan, Institute of Phytochemistry, 470032 Karaganda, ul. Gazalieva, 4 |
| Abstract: | 1,10-Dihydro-1 ,10-dinitrogrossmisin was synthesized by bubbling gaseous nitrosyl chloride through a chloroform solution of the guaianolide grossmisin. The molecular structure was determined by X-ray. It was found that the formation of similar dinitrates is accelerated by using NOCl containing nitrogen dioxide. |
| Keywords: | sesquiterpenoids guaianolides grossmisin achillin nitrosochlorination nitro compounds |
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