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Neue ternäre Phosphide und Arsenide des Caesiums mit Elementen der 8. Nebengruppe
Authors:A Czybulka  M Noack  H-U Schuster
Abstract:New Ternary Phosphides and Arsenides of Cesium and Element of the 8th Transition Metal Group In the ternary systems Cesium/8th transition metal group/5th main group some new compounds were found and investigated. By single crystal measurements CsRh2P2 was found to crystallize in the space group 14/mmm with the lattice constants a = 390.11 pm and c = 1429.36 pm. The new compounds with the formula CsM2X2 (M = Fe, Co, Ru, Rh, Ir; X = P or As) crystallize in the ThCr2Si2-type structure, compounds of the formula Cs2MX2 (M = Ni, Pd, Pt; X = P or As) can be placed in a line with the K2PdP2-type structure.
Keywords:Ternary intermetallic compounds  cesium  crystal structures
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