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Retention behavior of ions in high performance ion chromatography: III effect of the nature of the cation on anion retention |
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| Authors: | Louis G. Daignault D. Paul Rillema |
| Abstract: | The affects of alkali metal cations on the retention behavior of halide ions has been investigated. In general, the retention times of the anions were found to decrease as the size of the metal ion increased, although an inversion was observed for the rubidium and cesium ions. A similar inversion has been reported for calculated anion polarizabilities. |
| Keywords: | High performance ion chromatography (HPIC) Anions, retention behavior Cations, effect of Cation hydration, effect of Anion polarizability |