A New Type of Divalent Europium Compound MEuPO4 (M = K,Rb, Cs), its Synthesis,Crystal Structure,and Properties |
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Authors: | Guo-Quing Wu Zhongjia Tang Yongxian Yu Pingdi Lin M Jansen K Knigstein |
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Institution: | Guo-Quing Wu,Zhongjia Tang,Yongxian Yu,Pingdi Lin,M. Jansen,K. Königstein |
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Abstract: | Phosphates MEuPO4 with M = K, Rb, and Cs were synthesized by the reduction of EuPO4 with alkali metal vapour under 1 Pa of argon pressure at 260–530°C in sealed tantalum or niobium lined glass tubes. All the compounds belong to the β-K2SO4 orthorhombic structure with a = 7.359(3), b = 9.630(4), c = 5.569(2) Å, V = 394.7(2) Å3 for KEuPO4, a = 7.462(3), b = 9.797(3), c = 5.649(2) Å, V = 413.0(2) Å3 for RbEuPO4 and a = 7.889(2), b = 10.099(2), c = 5.820(4) Å, V = 463.6(2) Å3 for CsEuPO4. Samples are stable and not hygroscopic in air at room temperature but hydrolyse to Eu5(PO4)3OH, hexagonal, a = 9.764(2), c = 7.262(2) Å, on heating in water and decompose to Eu3(PO4)2, hexagonal, a = 5.393(1), c = 19.838(3) Å, under argon at ca. 600°C. All the five compounds are paramagnetic. |
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Keywords: | Alkali europium orthophosphate |
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