| 纳米二氧化钛的量子尺寸效应及掺杂氧化锡对其光吸收的影响 |
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| 引用本文： | 周华军,王大志,刘金华.纳米二氧化钛的量子尺寸效应及掺杂氧化锡对其光吸收的影响[J].化学物理学报(中文版),2002,15(1):61-64. |
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| 作者姓名： | 周华军 王大志 刘金华 |
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| 作者单位： | 中国科学技术大学材料科学与工程系,合肥,230026
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| 摘 要： | 采用溶胶-凝胶法制备了量子尺寸的纳米氧化钛和锡掺杂的纳米氧化钛,经过不同温度的热处理得到不同尺寸的粉末样品.通过X射线衍射(XRD)和电子衍射(ED) 表征了不同样品的物相组成和粒径(3～12 nm),通过反射谱(RS)深入研究了纳米氧化钛的量子尺寸效应及掺杂氧化锡对于纳米氧化钛光吸收性质的影响.实验结果表明纳米氧化钛有明显的光吸收量子尺寸效应,掺杂氧化锡促进了二氧化钛的锐钛矿向金红石相的转变,降低了相变起始温度.由于相变和尺寸变化两方面相反的作用,掺杂氧化锡对于二氧化钛光吸收边的位移影响不大.
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| 关 键 词： | 二氧化钛 二氧化锡 光吸收 量子尺寸效应 |
The Photo-absorbency Effect of Size and Doping SnO2 in Nano TiO2 |
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| Zhou Huajun,Wang Dazhi,Liu Jinhua.The Photo-absorbency Effect of Size and Doping SnO2 in Nano TiO2[J].化学物理学报(中文版),2002,15(1):61-64. |
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| Authors: | Zhou Huajun Wang Dazhi Liu Jinhua |
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| Abstract: | Quantum-sized Titania and SnO2-doped Titania were prepared by Sol-Gel method. After heat treatment at different temperatures, powder samples with different sizes (3~12 nm) were obtained. These samples were characterized with X-ray diffraction, eletron diffraction and reflect spectrum. Experiment shows that doped SnO2promotes the anatase→rutile phase transformation process, and reduced the temperature of phase transition. The doped SnO2restrain the growth of nano crystals of TiO2. Quantum-size effect of nano-Titana was observed. But shift of optical absorption edge was not so apparent when concentration of SnO2changed. Probable reasons were discussed. |
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| Keywords: | Titania Tin oxide Absorption Quantum size effect |
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